applications of coordination compounds ppt

applications of coordination compounds ppt

Crystal Field Theory (theory of pure electrostatic interactions So ligands must have lone pairs of electrons. The binding between metal and ligands is studied in metals, tetrahedral, and octahedral structures. Vanadium coordination compounds as insulin mimics. Chemistry Notes for class 12 Chapter 9 Coordination Compounds Coordination compounds are those addition molecular compounds which retain their identity in solid state as well as in dissolved state. (I) Applications of coordination compounds in analytical chemistry: Coordination compounds have many applications in qualitative as well as quantitative chemical analysis. The applications of coordination compounds has been grown widely due to their wide range in household, industry, medicine and chemical and biochemical systems but here we study only the applications of coordination compounds in industry and analysis in different branches of chemistry. • Compounds containing complexes are coordination compounds. Coordination compounds in analytical chemistry 1131 factor can introduce problems when washing the filtered-off precipitate to remove excess reagent, and a good deal of effort has gone into modifying the structure of some important precipitants (e.g. 0000161214 00000 n *IP����H��6եԈ�P3jA�� ���d�M��Pʠ��,��@�i( �Q4��i���i"�FSi:͠�4�ޢ��6-�wh��wi#m������~:H��Ot�N�)�}N_З�7�}M��ݢo�.�ҿ�'zH�3�rW皜�)\���ܔ�'�5��߰�:[�4?����Yܓ{q_�σx?�#����/���%���x ISBN 978-1-83880-057-4, eISBN 978-1-83880-058-1, PDF ISBN 978-1-83880-727-6, Published 2020-07-08 Uses of coordination compounds also involve their application as catalysts. Many metal-containing compounds, especially those of transition metals, are coordination complexes. [���$�FRdMeme�l���]�Џ�r�P���V�.7�V��>:${. 0000001968 00000 n Cordination compound 1. Outline History Bonding MO theory, VSEPR Compounds Applications Future Work History of Noble Gas Compounds Before 1962: all ... Ed. The design of coordination (metal) complexes is not an easy task. Ligands are either anions or molecules that can donate electrons into the d-orbitals of the metal ion and form a bond. The applications of coordination compounds in analytical chemistry as follows: (a) In the qualitative methods of analysis, complex formation is of immense importance in the identification and separation of most inorganic ions. It can also be described as a polymer whose repeat units are coordination complexes. Vocabulary. Dec 24, 2020 - Doc: Importance and Applications of Coordination Compounds Class 12 Notes | EduRev is made by best teachers of Class 12. Lastly, we also know how the coordination compound works in the applications. The pgms reappear in Chapter 13 (R. J. It was mentioned in section 3.3 that conformational analysis was performed on coordination complexes as early as on organic com-pounds. x�b```f``Y�������A��X��,= 0000164212 00000 n perfect preparation. ,�݇�@U�+�U�U! Chem210/chapter 3/2014/01. Ligands are either anions or molecules that can donate electrons into the d-orbitals of the metal ion and form a bond. The chemical composition of the dimer can be expressed as [RhCl(PPh 3) 2] 2; Preparation of Wilkinson’s Catalyst Brazier JN(1). All Time Show: Recommended. 0000162412 00000 n … It also failed to throw a light on the differences between strong and weak ligands. The characteristic properties possessed by coordination compounds that were discussed in the previous subsection make them extremely useful in various processes and industries. There are complexes that find the application of coordination compounds in photography. This is the only naturally occurring organometallic compound found in biology. This is "08 Importance and Applications of Coordination Compounds" by Sanjay on Vimeo, the home for high quality videos and the people who love them. 0000080429 00000 n Coordination compound • Complex compounds are a special class of compounds in which the metal atoms (or) ions are bound to a number of anions (or) neutral molecules. These compounds are of medicinal significance and are being used in various chemical analyses. 2. 0000114513 00000 n Transition Metal Coordination Chemistry Prof S.M.Draper 2.05 SNIAMS Building [email protected] Recommended books M.J. Winter, d-block Chemistry, Oxford Chemistry Primers, OUP, 2001 M.S. V15 Possible Applications of Coordination Compounds for Correcting Biometal Metabolism in Different Pathologies A. S. GRIGORIEVA, N. F. KONAKHOVICH and L. I. BUDARIN The L. V. Pisarzhevsky Institute of Physical Chemistry of the Ukrainian SSR Academy of Sciences, Kiev, US.S.R. Chelation takes topographic point when ligands “ bite ” or “ bee sting ” the metal in more than one topographic point at a clip. 0000001116 00000 n ��o�,.�y���^�+y ��˂�C�P5X6� zW���r��0"pu�,AF�Մ�!��P��P-X>� ISBN 978-1-83880-057-4, eISBN 978-1-83880-058-1, PDF ISBN 978-1-83880-727-6, Published 2020-07-08 . Significant progresses have been made in the inorganic and organic chemistry up to the present concerning the synthesis, characterization, and application of the metal complexes of pharmaceutical substances. COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev notes for Class 12 is made by best teachers who have written some of the best books of A coordination compound (or coordination complex) consists of a metal cation or neutral atom to which neutral or negatively charged ligands have bonded. 0000006306 00000 n the central metal atom or ion is linked by ions or molecules with coordinate bonds. This document is highly rated by Class 12 students and has been viewed 1229 times. World's Best PowerPoint Templates - CrystalGraphics offers more PowerPoint templates than anyone else in the world, with over 4 million to choose from. Dec 24, 2020 - Doc: Importance and Applications of Coordination Compounds Class 12 Notes | EduRev is made by best teachers of Class 12. Medicinal Applications of Coordination Chemistry begins with a brief historical review and an introduction to the chemistry of d- and f- block metals. The brilliant and intense colours of many coordination compounds, such as Prussian blue, render them of great value as dyes and pigments. Jan 04, 2021 - COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev is made by best teachers of Class 12. Transition Elements (Metals): A Survey Show great similarities within a given period as well as within a given vertical group. EDTA is another complex compound we use for the determination of hardness of water. 0000001433 00000 n These days, they are becoming increasingly popular in the polymer industry as well. Coordination compounds in industry. just for education and the COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev images and diagram are even better than Byjus! Applications of coordination complexes in industry. A major application of coordination compounds is their use as catalysts, which serve to alter the rate of chemical reactions. %PDF-1.3 %���� During the last two decades laboratory (with animals) and clinical researches have shown that many … Magnetic Properties of Coordination Complexes μ eff = 2√S(S+1) = √n(n+2) BM If there is a possibility for contribution from the orbital angular momentum, μ= √L(L+1) + 4S(S+1) For a given value of the orbital quantum number l, the magnetic quantum number m can have any values from –l to +l and L = sum of m For d orbital electrons,orbital electrons, m = 2, 1, 0,2, 1, 0, -1, -2 The document COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev is a part of. Coordination Compounds: Chemistry and Application Introduction Coordination compounds are metal ions surrounded by ligands. Author information: (1)The Mersey White Lead Co. Ltd., Sankey Bridges, Warrington, England. Classify the ligands based on charge, mode of bonding and density. �04�6TV�@���u���#t\�;���a�����&�5��"�`�p�!l � ÁB���80\xhQ��/ I have started with the "drier" complexometric quantitative analytical applications and then moved on to topics that students say are among their favorites in the whole book. 0000001635 00000 n 0000003167 00000 n 3 In 1845 Michael Faraday noticed that different compounds behaved differently in a magnetic field. porphyrins--complexes derived from porphine . Medical Applications of Coordination Chemistry Ranade, Vasant V PhD American Journal of Therapeutics: November-December 2007 - Volume 14 - Issue 6 - p 592 Coordination compounds play a vital role in analytical chemistry, metallurgy, biological systems, industry and medicine. dimethyl-glyoxime) with a view to increasing the solubility of the reagent without Transcript Coordination Chemistry PPT Chemistry of Coordination Compounds Chemistry of Coordination Compounds Complexes • A central metal atom bonded to a group of molecules or ions is a metal complex. Coordination compounds are a class of compounds that we know as the complex compounds. There are many applications of coordination compounds in modern day society, including metallurgy, therapeutic chelating agents, chemical analysis, catalysis, and detergents. 0000163591 00000 n 1. We know that transition metals have this special property of forming coordination complexes. The topics are broad and you will have to make some choices to narrow down the topic to fit this activity. Describe the constituents in a coordination compound and name the given complex compound. 0000165402 00000 n ]�cCq0C�t�E�C+_�n�q�x��� �&�K�oB���PX*|� '�"�j�m��j�߁�@��2��=�Q� Author information: (1)The Mersey White Lead Co. Ltd., Sankey Bridges, Warrington, England. KK���5�m Predict the geometry of coordination compounds. deoxyhemoglobin--the sixth ligand is a water molecule which can be easiy replaced by molecular oxygen. This is due to the high charge to mass ratio and also the availability of d-orb… Ligand Field Theory (adaptation of MO theory) ! Medical Applications of Coordination Chemistry Ranade, Vasant V PhD American Journal of Therapeutics: November-December 2007 - Volume 14 - Issue 6 - p 592 Chelation takes place when ligands “bite” or “bee sting” the metal in more than one place at a time. Many international researchers have strived to understand the mechanism of action or improve the efficacy of inorganic coordination compounds that have been identified to exhibit anticancer activity. 1969 Jul;16(7):949-66. Here you can download the free Engineering Chemistry Pdf Notes – EC Pdf Notes materials with multiple file links to download. COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev chapter (including extra questions, long questions, short questions, mcq) can be found on EduRev, you can check Stability and Applications of Coordination Compounds. In these compounds. Coordination compounds are important for at least three reasons. This is because of the chemistry that involves these compounds. Winner of the Standing Ovation Award for “Best PowerPoint Templates” from Presentations Magazine. S�gB�`��*� ;@4D�������!�B �ρ�‰@�"�a�\h�(�ӄ�A��(PT�&L�-��B�Z0mx��EGh�t���#pt(B�?= Increasingly, coordination compounds are being used to provide functionality, as well as decorative effect in coatings and surface finishes. 0000166034 00000 n From the wide range of fields in which these coordination compounds find their application, many efforts were focused on the study of their importance in the biological processes. You can download Free COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev pdf from EduRev by • Purifications of metals. Complete CHEM210/Chapter 3/2014/01. It has gotten 9070 views and also has 4.8 rating. Valence bond theory ! This document is highly rated by Class 12 students and has been viewed 1229 times. coordination compounds: ! CHEM 160 General Chemistry II Lecture Presentation Coordination Chemistry - Lecture Presentation Coordination Chemistry Chapter 24 April 25, ... NH3 = ammine carbon ... magnetism. Coordination Complexes as Catalysts The first half of the book focuses on the use of coordination complexes as catalysts for a diverse range of organic reactions. Chapter 3: Coordination Chemistry. The role of metal complexes in photography, electrophotograpy and ink-jet printing are concisely described. Examples of common You can also find COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev ppt and other Class 12 slides as well. 0000164888 00000 n This presentation is all about acid, base and salt of class 7 from cbse science book.it have the detailed explanation about concept of acid that is definition of acid, types of acid and various examples of acid from day to day life.these concepts are very well explained with adequate examples and animated images. By continuing, I agree that I am at least 13 years old and have read and agree to the. 0000177731 00000 n This is 0000220543 00000 n The valence bond theory could not explain the stability of the coordination compounds. Critical Thinking Questions. Subsequent sections discuss metallodrugs for a number of different applications, the design of new drugs … Grignard Reagents Market Research Report 2020 - Download Free [email protected] https://bit.ly/2SpaOK9 #ChemicalsMarket #MarketAnalysis #Chemicals #ChemicalsAndMaterial Grignard Reagents are a class of organometallic compounds representing a standard formula R-Mg-X, wherein R is an organic group and X is an atom belonging to the halogen group. The uses of metal complex compounds in the various fields of analytical chemistry are reviewed with particular reference to newer reagents and fresh applications of established reagents. V15 Possible Applications of Coordination Compounds for Correcting Biometal Metabolism in Different Pathologies A. S. GRIGORIEVA, N. F. KONAKHOVICH and L. I. BUDARIN The L. V. Pisarzhevsky Institute of Physical Chemistry of the Ukrainian SSR Academy of Sciences, Kiev, US.S.R. 0000157285 00000 n H1��ui5 �+�c �R��n2� a��^ ��I�-��K�2dA�)�I�)��������&KK,�>S�&+��[email protected]�̷�&�f��&M���-�Pb�� > endobj 45 0 obj<>/Font<>>>/DA(/Helv 0 Tf 0 g )>> endobj 46 0 obj<> endobj 47 0 obj<>/ProcSet[/PDF/Text/ImageB]/ExtGState<>>> endobj 48 0 obj<> endobj 49 0 obj<> endobj 50 0 obj<> endobj 51 0 obj<> endobj 52 0 obj<> endobj 53 0 obj<> endobj 54 0 obj<> endobj 55 0 obj<>stream Due to tetrahedral coordination by weak-field sulfur ligands, the iron is high spin in both the Fe 3 + and Fe 2 + oxidation states, which results in similar structures for the oxidized and reduced forms of the Fe–S complexes. Second, many industrial catalysts are metal complexes, and such catalysts are steadily becoming more important as a way to control reactivity. There are many pharmaceutical and biological applications of coordination complexes and their isomers. Infrared and Raman Spectra of Inorganic and Coordination Compounds: Part B: Applications in Coordination, Organometallic, and Bioinorganic Chemistry, Sixth Edition Related Information 0000157194 00000 n 1. EduRev is a knowledge-sharing community that depends on everyone being able to pitch in when they know something. 6.1 Applications of Monodentate Complexes 6.2 Two Keys to the Stability of Transition Metal Complexes Hard and Soft Acids and Bases The Chelate Effect 6.3 Applications of Multidentate Complexes 6.4 Chelating Agents as Detergent Builders Wilkinson’s catalyst has a square planar coordination geometry; It reacts with carbon monoxide to yield [RhCl(CO)(PPh 3) 2] This coordination compound undergoes dimerization when stirred into a solution of benzene. Sort by: Synthesis of ... - Ed. 0000001511 00000 n 2. the examples are very well explained for each individual illustration. 0000006472 00000 n Analytical applications of co-ordination compounds. A coordination complex consists of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Presentation Summary : CHAPTER 3: COORDINATION CHEMISTRY. Appreciate various bonding theories developed to describe nature of bonding in complex compounds. 1999, 38, 2554. EduRev is like a wikipedia the applications of coordination chemistry since 1982. Valence bond theory ! Edited by: Abhay Nanda Srivastva. Examples of common ligands are chloride ion, cyanide ion, ammonia, ethylenediamine, and ethylenediaminetetraacetate ion (EDTA). Ligand Field Theory (adaptation of MO theory) ! Application of Coordination Compounds with Transition Metal Ions in the Chemical Industry-A Review. To Study COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev for Class 12 The applications of coordination compounds in chemistry and technology are many and varied. • If the complex bears a charge, it is a complex ion. Chemistry of Coordination Compounds Applications of coordination compounds Coordination compounds are used for many applications : • Extraction processes of gold and silver. A coordination compound, sometimes called a coordination … compounds which retain their identities even when dissolved in water or in any other solvent where the properties are completely different from those of the individual components are called Coordination Compounds The organic chemist often deals with diamagnetic compounds which are The uses of metal complex compounds in the various fields of analytical chemistry are reviewed with particular reference to newer reagents and fresh applications of established reagents. of COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev for Class 12, the answers and examples explain the meaning of chapter in the best manner. Coordination Compounds Chapter 20. 0000220377 00000 n Overview of Applications Of Coordination Compounds. 0000159213 00000 n subunits--folded long chains. Applications of coordination compounds (in chemistry, life,industry) 42 0 obj <> endobj xref 42 41 0000000016 00000 n 0000042820 00000 n e.g., Potassium ferrocyanide, K 4 [Fe(CN) 6]. 0000002058 00000 n First, most of the elements in the periodic table are metals, and almost all metals form complexes, so metal complexes are a feature of the chemistry of more than half the elements. using search above. A History of Medicine, Taylor & Francis Group, LLC, Boca Raton. 2 Review of the Previous Lecture 1. They'll give your presentations a professional, memorable appearance - the kind of sophisticated look that today's audiences expect. Therefore, scientists proposed the crystal field theory.According to this theory, the metal-ligand bond acts as an Valence Bond theory • Just like we learned before. A really particular application of coordination compounds occurs in what is called the chelate consequence. REFERENCE : 1. Coordination compounds have applications in day-to-day life. Talanta. Analytical applications of co-ordination compounds. coordination compounds are being used to pro-vide functionality, as well as decorative effect in coatings and surface finishes. Consequently, only small structural changes occur after oxidation or reduction of the Fe–S center, which results in rapid electron transfer. If you want COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev • Used as catalysts in many industrial processes. Irving Department of Inorganic Chemistry, University of Cape Town, Rondebosch, Cape Town, South Africa Abstract - Coordination compounds are used in almost every branch of analytical chemistry. 0000004213 00000 n Technetium radiopharmaceuticals for imaging the body with respect to function. Applications of Coordination Compounds The sections and subsections in this chapter are listed below. • In modern terminology, these compounds are called coordination compounds. The applications of coordination compounds involving multidentate ligands are again so myriad that I have had to choose among them. your solution of COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev search giving you solved answers for the same. A very special application of coordination compounds occurs in what is called the chelate effect. Using dental “biting” terminology, if a ligand has two “teeth” to bite a transition metal, it is called a bidentate (two teeth) ligand. coordination compounds: ! ǀb"taz��8&�Ӈ�@W�XPl�>� � 0000157954 00000 n The structures of certain coordination compounds can also have isomers, which can change their interactions with other chemical agents. (When copper sulphate solution is mixed with aqueous ammonia, a deep blue complex soluble in water is formed. 0000114346 00000 n The inherent challenges of chemotherapy demand that new strategies be developed utilising different mechanisms of action to interrupt the cellular machinery of cancer cells. COORDINATION COMPOUNDS IN ANALYTICAL CHEMISTRY Harry M.N.H. Edited by: Abhay Nanda Srivastva. 0000160104 00000 n Objective was achieved. Coordination complexes can undergo a variety of reactions, including electron transfer, ligand exchange, and associative processes. 0000160167 00000 n Some of these applications of coordination compounds can be found below. 0000001814 00000 n A coordination polymer is an inorganic or organometallic polymer structure containing metal cation centers linked by ligands.More formally a coordination polymer is a coordination compound with repeating coordination entities extending in 1, 2, or 3 dimensions. ׂj� The applications of coordination compounds as catalysts in industrial processes as follows: (a) In the polymerisation of ethene, The Ziegler-Natta catalyst is used which is a combination of titanium tetrachloride and tri ethyl aluminium. 0000002120 00000 n 0000005260 00000 n The factors which make them specially suitable for gravimetric and titrimetric analysis, 23.7 Applications of Coordination Compounds. Tests & Videos, you can search for the same too. Due to tetrahedral coordination by weak-field sulfur ligands, the iron is high spin in both the Fe 3 + and Fe 2 + oxidation states, which results in similar structures for the oxidized and reduced forms of the Fe–S complexes. The colour of the coordination compounds containing transition metals causes them to be extensively used in industries for the colouration of materials. Brazier JN(1). They find applications in the dye and pigment industries. Crystal Field Theory (theory of pure electrostatic interactions So ligands must have lone pairs of electrons. Coordination Compounds: Chemistry and Application Introduction Coordination compounds are metal ions surrounded by ligands. • Hardness of water (EDTA). Chapter 19 Coordination Complexes 19.1 The Formation of Coordination Complexes 19.2 Structures of Coordination Complexes 19.3 Crystal- Field Theory and Magnetic Properties 19.4 The Colors of Coordination Complexes 19.5 Coordination Complexes in Biology C1403 Lecture 20 Tuesday, November 16, 2005 Infrared spectroscopy (IR tutor) 2 H2O Ni H2O H2O H2O H2O H2O H 3N Ni H 3N NH NH NH3 … 0000156846 00000 n Coordination Compounds in Biology Vitamin B 12 is an important coordination compound in biol-ogy. Discussed different bonding theories to explore metal ligand bonding in coordination compounds 2. Class 12. |���NK``�_}T]�hl�1�8�6��C��-��~6%�y�\Y|L�&��n/�4-f]׬�Ť��� Applications Of Organometallic Compounds PowerPoint PPT Presentations. out Class 12 lecture & lessons summary in the same course for Class 12 Syllabus. Valence Bond theory • Just like we learned before. Explored electronic transitions in coordination compounds using the different bonding theories. 1999, 38, 2554. 0000159907 00000 n Certain complex metal catalysts , for example, play a key role in the production of polyethylene and polypropylene . The role of metal complexes in photography, electrophotograpy and ink-jet printing are concisely described. structural and stereoisomerism in coordination compounds ( octahedral and tetrahedral and square planer complexes ) It is an interesting biomolecule in the sense that no other vitamin contains a metal ion. 0000158557 00000 n H�L�yt�W���$Ac���%C�:�-UK����K��}��tL۱Վ)���e�Ҙi"i����s�{�����~=$bXQ��^�{������>�H���wžԄ��q�c��]),���s4)5�D�Ը�䕍�8����.�/��"I��DC�*�Ds�R�"*4a�����,��"S�٢��'���01B�1b�xQ�^�"^��4�)�B1_,Eb�X!V�ub��$��b��+�C��H��I�8-Έs₸$.�+�(��qO�?�2Q. Inorganic compounds have been used in medicine for thousands of years, often without a known molecular basis for their mechanism of action, and with little attempt to design them. This document is highly rated by Class 12 students and has been viewed 9053 times. From this App you can learn : Differentiate double salts and coordinate compounds. Orvig C, Abrams MJ (1999) Medicinal inorganic chemistry: introduction. heme group--the iron-porphyrin combination. 0000042654 00000 n trailer <<44976c00d6be11d8bc2a003065ef6f20>]>> startxref 0 %%EOF 44 0 obj<>stream Outline History Bonding MO theory, VSEPR Compounds Applications Future Work History of … 0000157012 00000 n We have known enough about these compounds already, including their structuresand isomers etc. Class 12 COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev Summary and Exercise are very important for coordination: The reaction of one or more ligands with a metal ion to form a coordination compound. We apply the concept of coordination compounds in the … The number of ligand atoms to which the metal center is directly bonded is the metal cation’s coordination number (c.n. Coordination Compounds Isomerism Bonding in Complex Ions: The Localized Electron Model The Crystal Field Model The Biologic Importance of Coordination Complexes Metallurgy and Iron and Steel Production Transition Metals and Coordination Chemistry . Stability and Applications of Coordination Compounds. You can see some COORDINATION COMPOUNDS- PowerPoint Presentation, Science, Chemistry, class 12 Class 12 Notes | EduRev sample questions with examples at the bottom of this page. A Coordination Compound, Sometimes Called PPT. July 2020 ; International Journal of Molecular Sciences; DOI: 10.3390/ijms21155443. Magner L (2005) Native Civilizations and Cultures of the Americas. Coordination compound By azim 2. M�m"�`��h*l�#��B�`�!< ��AŒ�ӡ�]��Qx4��0 Key Terms. redox: A reversible chemical reaction in which one reaction is an oxidation and the reverse is a reduction. Do check out the sample questions 0000080263 00000 n this is your one stop solution. It follows on from the review of Volume 6, published in our April issue (1). 0000157103 00000 n

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